Analysis of changes in water quality chemical parameters in the Bafgh watershed

Authors
1 Associate Professor, Soil Conservation and Watershed Management Research Department, Fars Agricultural and Natural Resources Research and Education Center, Agricultural Research, Education and Extension Organization (AREEO), Shiraz, Iran
2 Assistant Professor, Desert Research Department, Research Institute of Forests and Rangelands, Agricultural Research, Education and Extension Organization (AREEO), Tehran, Iran.
3 Assistant Professor, Soil Conservation and Watershed Management Research Department, Kurdistan Agricultural and Natural Resources Research and Education Center, Agricultural Research, Education and Extension Organization (AREEO), Sanandaj, Iran.
4 Ph.D., Natural Resources and Watershed Management Department, Bafgh County, Yazd Province, Iran.
10.22034/wmji.2025.2065092.1120
Abstract
Groundwater is the primary source of water for domestic, agricultural and industrial use in many countries, and its quality reduction is recognized as one of the most serious problems. The quality of underground water depends on the nature of bedrock, topography, geology, soil, climate, atmospheric precipitation and the quality of fed water and sources of human pollution in terms of agricultural and industrial activities. In addition, groundwater quality can be affected by subsurface geochemical reactions such as weathering, dissolution, precipitation, ion exchange, and various biological processes. For this purpose, the current research was conducted with the aim of investigating the chemical water quality of Bafgh watershed. The necessary data and information on the chemical quality of underground water sources were obtained by referring to the Iranian Water Resources Research Organization and the Regional Water Organization of Yazd and Kerman Provinces in a joint statistical period of 17 years from the water year 2002-2003 to the water year 2017-2018. In order to determine the type of water, the sequence of the dominance of anions and cations, and to determine the hydrochemical processes and chemical compositions of water, Piper's diagram has been used. By using composite and Gibbs diagrams, the type and facies of underground water were determined and their causes were investigated. The results of the Piper diagram showed that the dominant type and facies in the basin is of the Sodic chloride type, which indicates the salinity of the underground water in this area. The results of the composite diagrams show that the process of evaporation, dissolution of halite, cation exchange, weathering and dissolution of rocks and minerals, especially carbonates such as calcite, dolomite and to a lesser extent gypsum and silicates, also, agricultural activities and the infiltration of return saline water from agriculture are factors affecting the chemical quality of underground water.
Keywords

  1. Arom. Z., Forghani Tehrani, G., and Kazami. A. 2018. Investigation of Hydrogeochemistry and quality of Groundwater in the Aquifer of Bukan Plain, West Azerbaijan Province. Advanced Applied Geology, 8(1), 13-32. (In Persian).
  2. Azizi, F., Arjomand, H., MoradiNejad, T., and Khazaei, M. 2020. Evaluation of Groundwater Hydro-geochemical Characteristics in Basht Plain Aquifer and its Suitability using Qualitative Indicators. Extension and Development of Watershed Management, 8(28), 57-65. (In Persian).
  3. Bai, X., Tian, X., Li, J., Wang, X., Li, Y., and Zhou, Y. 2022. Assessment of the Hydrochemical Characteristics and Formation Mechanisms of Groundwater in a Typical Alluvial-Proluvial Plain in China: An Example from Western Yongqing County. Water, 14(15), 2395
  4. Chen, Z., Grasby, S., and Osadetz, K.G. 2004. Relation between climate variability and groundwater level in the upper carbonate aquifer, south Manitoba, Canada, Journal of Hydrology, 290: 62-43.
  5. Elshorbagy, A., and Ormsbee, L. 2006. Object-oriented modeling approach to surface water quality management. Environmental Modelling & Software, 21(5), 689-698.
  6. Esmaeili, S., Barzegar, R., and Kazemian, N. 2018. The effective factors on the groundwater chemical quality of Qareh-Ziaeddin plain, West Azarbaijan province.  Journal of Geosciences, 27(108), 245-256. (In Persian).
  7. Faryabi, M., Kalantari, N., and Negarestani, A. 2010. Evaluation of factors influencing groundwater chemical quality using statistical and hydrochemical methods in Jiroft plain.  Journal of Geosciences, 20(77), 115-120. (In Persian).
  8. Gabr, M. E., Soussa, H., and Fattouh, E. 2021. Groundwater quality evaluation for drinking and irrigation uses in Dayrout city Upper Egypt. Ain Shams Engineering Journal, 12(1), 327-340.
  9. Gibbs, R. J. 1970. Mechanisms controlling world water chemistry. Science, 170(3962), 1088-1090.
  10. Gholamdokht Bandari M, Rezaee P, and Gholamdokht Bandari Z. 2018. Assessment of the hydrogeochemical quality of underground in the Siahoo region, northeast of Bandar Abbas. Iranian Journal health and environment, 11 (1), 97-110. (In Persian).
  11. Gupta, S., Mahato, A., Roy, P., Datta, J. K., and Saha, R. N. 2008. Geochemistry of groundwater, Burdwan District, West Bengal, India. Environmental Geology, 53, 1271-1282.
  12. Hassanzadeh, N. M., and Khajebafghi, H.  2017. Flood Hazard Zoninig Using Multiple Criteria Decision Analysis System (Case Study: Sheytoor Watershed in Bafgh). Journal of Watershed Management Research, 7(14), 37-29. (In Persian).
  13. Jafarian, H., Vaezihir, A., and Pirkharrati, H. 2018. The Determination of the Influential Parameters in Hydrochemistry of Hard Rocks and Karstic Groundwater in the West of Urmia,Iran. Hydrogeomorphology, 5(1), 75-94. (In Persian).
  14. Jia, H., Qian, H., Zheng, L., Feng, W., Wang, H., A., Gao, Y. 2020. Alterations to groundwater chemistry due to modern water transfer for irrigation over decades. Science of the Total Environment, 717, 137170.
  15. Ismail, E., Snousy, M. G., Alexakis, D. E., Abdelhalim, A., Ahmed, M. S., A., Elsayed, E. 2023. Diagnosis of Groundwater Quality in North Assiut Province, Egypt, for Drinking and Irrigation Uses by Applying Multivariate Statistics and Hydrochemical Methods. Water, 15(15), 2812.
  16. Kalantari, N., Rahimi, M.H., and Churchy, A. 2007. Use of Composite Diagrams, Factor Analysis and Saturation Index for Quantification of Zeviercherry & Kheran Groundwater Plains. Journal of Engineering Geology, 2(1), 339-356. (In Persian).
  17. Liu, J., Gao, Z., Wang, Z., Xu, X., Su, Q., Wang, S., Qu, W., and Xing, T. 2020. Hydrogeochemical processes and suitability assessment of groundwater in the Jiaodong Peninsula, China. Environmental Monitoring and Assessment, 192, 1-17.
  18. Merino, L. M., Aguilera, H., González-Jiménez, M., and Díaz-Losada, E. 2021. D-Piper, a modified piper diagram to represent big sets of hydrochemical analyses. Environmental Modelling & Software, 138, 104979.
  19. Moghimi, H. 2015. Assessment of Hydrochemical Characteristics of Groundwater Resources of the aquifer of the Sari-Ghaemshahr plain for Drinking and Irrigation Purposes. Water Resources Engineering, 8(26), 51-68. (In Persian).
  20. Ravikumar, P., Somashekar, R. K., and Prakash, K. L. 2015. A comparative study on usage of Durov and Piper diagrams to interpret hydrochemical processes in groundwater from SRLIS river basin, Karnataka, India. Earth Science, 80(2015), 31073-31077.
  21. Reddy, A. G. S., Saibaba, B., and Sudarshan, G. 2012. Hydrogeochemical characterization of contaminated groundwater in Patancheru industrial area, southern India. Environmental Monitoring and Assessment, 184, 3557-3576.
  22. Soltani, S., Asghari Moghaddam, A., Barzegar, R., and Kazemian, N. 2017. Identifying Effective Processes on Groundwater Chemistry of the KordkandiDuzduzan Plain Aquifer. Journal of Water and Soil, 27(2),77-89.
  23. Shyam, R., Krishan, G., Kheraj, and Kumar, A. 2022. Evaluation of groundwater quality for life-supporting activities: a case study of Haryana, India. International Journal of River Basin Management, 1-12.
  24. Taoufiq, L., Kacimi, I., Saadi, M., Nouayti, N., Kassou, N., Bouramtane, T., A., El-Mouhdi, K. 2023. Assessment of Physicochemical and Bacteriological Parameters in the Angads Aquifer (Northeast Morocco): Application of Principal Component Analysis and Piper and Schoeller–Berkaloff Diagrams. Applied and Environmental Soil Science, 2023.
  25. Tong, X., Tang, H., Gan, R., Li, Z., He, X., and Gu, S. 2022. Characteristics and causes of changing groundwater quality in the boundary line of the middle and lower Yellow River (right bank). Water, 14(12), 1846.
  26. Yang, J., Liu, H., Tang, Z., Peeters, L., and Ye, M. 2022. Visualization of aqueous geochemical data using python and WQChartPy. Groundwater, 60(4), 555-564.
  27. Zhang, C., Li, X., Ma, J., Wang, Z., and Hou, X. 2022. Stable isotope and hydrochemical evolution of shallow groundwater in mining area of the Changzhi Basin, northern China. Environmental Earth Sciences, 81(10), 294.